In the presence of 2 6 dimethylpyridine as an added base living cationic polymerization of isobutyl vinyl ether was achieved in n hexane at 0 to 40 c with the 1 isobutoxy ethyl acetate 3. Studied systems are based on i 2 hi and on zinc halides zinc chloride zinc bromide and zinc iodide. The controlled introduction of end groups was confirmed by a model reaction and was then applied to introduce and azo initiator function.
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